Barrett, Anthony G. M. published the artcileApplications of Crotonyldiisopinocampheylboranes in Synthesis: Total Synthesis of Restrictinol, Name: (+)-B-Methoxydiisopinocampheylborane, the publication is Journal of Organic Chemistry (1999), 64(1), 162-171, database is CAplus and MEDLINE.
The total synthesis of restrictinol, the hydrolysis product of the antifungal natural product restricticin, starting from com. available Me (S)-(+)-3-hydroxy-2-methylpropionate was achieved. Key steps in the strategy involved (1) the use of Brown’s allylboration chem. to construct an acyclic intermediate bearing three of the four stereogenic centers of the natural product, (2) formation of a C-glycosidic vinyl iodide, and (3) introduction of the triene side chain via a Suzuki coupling reaction.
Journal of Organic Chemistry published new progress about 99438-28-5. 99438-28-5 belongs to ethers-buliding-blocks, auxiliary class Chiral,Aliphatic cyclic hydrocarbon, name is (+)-B-Methoxydiisopinocampheylborane, and the molecular formula is C21H37BO, Name: (+)-B-Methoxydiisopinocampheylborane.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem