Wang, Zijing published the artcileSynthesis of NHC Pincer Hydrido Nickel Complexes and Their Catalytic Applications in Hydrodehalogenation, Application In Synthesis of 622-86-6, the main research area is nickel bromide pincer complex hydrogenation hydride reagent; hydrido nickel pincer complex preparation catalyst alkyl halide hydrodehalogenation; crystal structure aminocarbeneamine nickel hydride pincer complex; mol structure aminocarbeneamine nickel hydride pincer complex.
The C(carbene)N(amino)N(amine)-pincer Ni(II) bromides (1a – 1c) were hydrogenated to the corresponding Ni(II) hydrides (2a – 2c) by (EtO)3SiH/NaOtBu or NaBH4. These Ni(II) hydrides (2a -2c) were characterized by NMR and IR spectroscopy as well as x-ray diffraction. The catalytic performance of complex 2b for hydrodehalogenation reactions was explored. In a combination of 3 mol% catalyst loading, (EtO)3SiH/NaOtBu/toluene/80° and different reaction time, organic halides were successfully reduced to the related alkanes. A catalytic radical mechanism is proposed and partly verified by experiments
Organometallics published new progress about Alkanes Role: SPN (Synthetic Preparation), PREP (Preparation). 622-86-6 belongs to class ethers-buliding-blocks, name is (2-Chloroethoxy)benzene, and the molecular formula is C8H9ClO, Application In Synthesis of 622-86-6.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem