Konishi, Hiroaki published the artcileInfluence of Electrolyte Composition on the Electrochemical Reaction Mechanism of Bismuth Fluoride Electrode in Fluoride Shuttle Battery, Product Details of C10H22O5, the main research area is fluoride shuttle battery bismuth fluoride electrode electrolyte composition.
Fluoride shuttle battery (FSB) is a promising next-generation battery candidate. In the FSB, metal fluoride and organic solvent containing supporting electrolyte salt and anion acceptor were used as active material and electrolyte. In this study, using bis[2-(2-methoxyethoxy)ethyl] ether (tetraglyme: G4) containing cesium fluoride (CsF; 0.45 mol dm-3 or saturated) and triphenylboroxine (TPhBX; 0.50 mol dm-3) as electrolyte (CsF(0.45)-TPhBX(0.50)-G4 and CsF(saturate)-TPhBX(0.50)-G4), the electrochem. performance of bismuth fluoride (BiF3) was assessed. Although the discharge and charge reactions of BiF3 electrode proceeded in both electrolytes, the cycling performance of BiF3 electrode in CsF(0.45)-TPhBX(0.50)-G4 was poorer than that in CsF(saturate)-TPhBX(0.50)-G4. The cause of differences in the electrochem. properties was investigated using at. absorption spectrometry (AAS), XPS, and cross-sectional SEM (SEM)/energy dispersive X-ray spectroscopy (EDX). The AAS results indicate that the poor cycling performance with CsF(0.45)-TPhBX(0.50)-G4 was due to the dissolution of active material during charging. The XPS and cross-sectional SEM/EDX results indicate that the formation state of Bi, and the progress of electrolyte decomposition during discharging were affected by the CsF/TPhBX ratio in the electrolyte.
Journal of Physical Chemistry C published new progress about Carbon black Role: TEM (Technical or Engineered Material Use), USES (Uses). 143-24-8 belongs to class ethers-buliding-blocks, name is 2,5,8,11,14-Pentaoxapentadecane, and the molecular formula is C10H22O5, Product Details of C10H22O5.
Referemce:
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Ether | (C2H5)2O – PubChem