He, Zhen published the artcileSulfoxide-mediated oxidative cross-coupling of phenols, Quality Control of 121-00-6, the main research area is phenol nucleophile sulfoxide mediator oxidative cross coupling regioselective; arylphenol preparation; benzofuran preparation; hydroxy teraryl preparation.
A metal-free, oxidative coupling of phenols with various nucleophiles, including arenes, 1,3-diketones and other phenols was reported. Cross-coupling was mediated by a sulfoxide which inverts the reactivity of the phenol partner. Crucially, the process showed high selectivity for cross-vs. homo-coupling and allowed efficient access to a variety of aromatic scaffolds including biaryls, benzofurans and through an iterative procedure aromatic oligomers.
Chemical Science published new progress about Benzofurans Role: PRP (Properties), SPN (Synthetic Preparation), PREP (Preparation). 121-00-6 belongs to class ethers-buliding-blocks, name is 4-Hydroxy-3-tert-butylanisole, and the molecular formula is C11H16O2, Quality Control of 121-00-6.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem