Delnick, Frank M. published the artcileInvestigation of Complex Intermediates in Solvent-Mediated Synthesis of Thiophosphate Solid-State Electrolytes, Category: ethers-buliding-blocks, the main research area is solvent mediated synthesis thiophosphate solid state electrolyte.
Lithium thiophosphates represent a promising class of solid Li+ conductors for all-solid-state batteries. Scalable solvent-mediated synthesis routes for several Li-P-S ternary compounds have been reported, but little is known regarding the reaction mechanism of such pathways. This work demonstrates that solvent-mediated synthesis of lithium thiophosphate solid electrolytes from mixtures of Li2S and P2S5 proceeds through a highly soluble P2S62- intermediate. This intermediate exhibits virtually the same Raman spectra in several solvents including acetonitrile, Me acetate, Et acetate, Et propionate, dimethoxyethane, tetraethylene glycol di-Me ether, and THF. Based on this universal intermediate, a general reaction mechanism is proposed for the solvent-mediated synthesis of several lithium thiophosphates including (LiPS3)n, Li2P2S6, Li7P3S11, and Li3PS4.
Journal of Physical Chemistry C published new progress about Solid electrolytes. 143-24-8 belongs to class ethers-buliding-blocks, name is 2,5,8,11,14-Pentaoxapentadecane, and the molecular formula is C10H22O5, Category: ethers-buliding-blocks.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem