Carreras, Lucas published the artcileSelective functionalisation of aromatic alcohols with supramolecularly regulated gold(I) catalysts, Recommanded Product: 2,5,8,11-Tetraoxatridecan-13-ol, the main research area is hydroxyaryl carbonyl derivative preparation gold catalyst; aromatic alc diazo ester carbon hydrogen insertion reaction.
Phosphite-based Au(I) catalytic systems containing an array of structurally diverse polyether-based regulation sites were designed and synthesized. These catalysts have been successfully tested in the Au(I)-catalyzed C-H functionalization of phenols and related derivatives with gold-carbenes derived from diazo compounds Regulation of the steric congestion around the catalytic Au(I) center via ion-dipole interactions with an external regulation agent led to an enhancement of both the activity and selectivity of the reaction. This new approach in supramol. gold(I) catalysis has been applied to the derivatisation of an array of substituted phenols and related substrates and to the preparation of an advanced synthetic intermediate of the anticancer agent tamoxifen. The effects of the regulation agent on the selectivity and yield of the reaction have been studied and rationalised using DFT-D calculations
Organic Chemistry Frontiers published new progress about Aromatic alcohols Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 23783-42-8 belongs to class ethers-buliding-blocks, name is 2,5,8,11-Tetraoxatridecan-13-ol, and the molecular formula is C9H20O5, Recommanded Product: 2,5,8,11-Tetraoxatridecan-13-ol.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem