Model Compounds Study for the Mechanism of Horseradish Peroxidase-Catalyzed Lignin Modification was written by Yang, Dongjie;Wang, Yalin;Huang, Wenjing;Li, Zhixian;Qiu, Xueqing. And the article was included in Applied Biochemistry and Biotechnology in 2020.Application of 103-16-2 The following contents are mentioned in the article:
Horseradish peroxidase (HRP) has demonstrated high activity for the modification of lignin. In this paper, several lignin model compounds with different functional groups and linkages are selected to investigate the reactivity of HRP-catalyzed lignin modification. The phenolic groups of lignin model compounds are indispensable for the HRP-catalyzed modification process. The introduction of the sulfomethylated Me group or methoxyl group could facilitate or inhibit the modification, resp. The oxidative coupling activity of α-O-4 lignin model compounds is higher than that of β-O-4 compounds Meanwhile, the free energy obtained by d. functional theory (DFT) is used to verify the results of the exptl. study, and the order of preference for linkages is β-5 > β-β > β-O-4 in most cases. In addition, electron cloud d. and steric hindrance of lignin model compounds have crucial effects on the oxidation and modification processes. Finally, the mechanism of HRP-catalyzed lignin modification is proposed. This study involved multiple reactions and reactants, such as 4-Benzyloxyphenol (cas: 103-16-2Application of 103-16-2).
4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Application of 103-16-2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem