Distorted zinc coordination polyhedra in bis(1-ethoxy-2-{[(2-methoxyethyl)imino]methyl}propan-1-olato)zinc, a possible CVD precursor for zinc oxide thin films was written by Johnson, Keneshia O.;Brown, Antionette;Farris, Gabriella;Starks, Alexabria;Butcher, Ray J.;Matthews, Jason S.. And the article was included in Acta Crystallographica in 2022.Related Products of 109-85-3 The following contents are mentioned in the article:
A new metal-organic precursor for the chem. vapor deposition of zinc oxide thin films, [Zn(C9H16NO3)2], has been synthesized and characterized by 1H and 13C NMR spectroscopy, single-crystal X-ray diffraction and thermogravimetric anal. The asym. unit of the title compound consists of two mols. (Z′ = 2), with different zinc coordination polyhedra. In one mol., the metal atom is in a distorted trigonal-bipyramidal ZnN2O3 environment (τ5 = 0.192) with a long bond to an ether O donor atom [Zn-O = 2.727 (6) Å]. In the other, the Zn atom is in a distorted ZnN2O4 octahedral environment with long bonds to the ether O donors of both ligands [Zn-O = 2.514 (4) and 2.661 (4) Å; O-Zn-O = 82.46 (14)°]. The crystal structure features weak C-H····O interactions. This study involved multiple reactions and reactants, such as 2-Methoxyethylamine (cas: 109-85-3Related Products of 109-85-3).
2-Methoxyethylamine (cas: 109-85-3) belongs to ethers. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Related Products of 109-85-3
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem