Ni-Catalyzed Cross-Electrophile Coupling of Aryl Triflates with Thiocarbonates via C-O/C-O Bond Cleavage was written by Zhu, Zhaodong;Gong, Yuxin;Tong, Weiqi;Xue, Weichao;Gong, Hegui. And the article was included in Organic Letters in 2021.Computed Properties of C13H12O2 The following contents are mentioned in the article:
A synthesis of aryl thioesters RCOSR1 (R = Ph, 4-MeO2CC6H4, 4-BnOC6H4, etc.; R1 = n-hexyl, cyclohexyl, cyclopentyl, etc.) via nickel-catalyzed reductive coupling of aryl triflates with thiocarbonates was reported. Both electron-rich and -deficient aryl C(sp2)-O electrophiles as well as a class of O-tBu S-alkyl thiocarbonates were compatible with the optimized reaction conditions as evidenced by 49 examples. The reaction also proceeded with good chemoselective cleavage of the C-O bond with regard to thioesters. This work broadened the scope of nickel-catalyzed reductive cross-electrophile coupling reactions. This study involved multiple reactions and reactants, such as 4-Benzyloxyphenol (cas: 103-16-2Computed Properties of C13H12O2).
4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Computed Properties of C13H12O2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem