Dehydrocoupling of boranes with amines using a scandium catalyst was written by Wang, Yang;Xu, Pengfei;Xu, Xin. And the article was included in Chinese Chemical Letters in 2021.SDS of cas: 109-85-3 The following contents are mentioned in the article:
The scandocene alkyl complex (C5Me5)2ScCH2SiMe3 was found to be an efficient catalyst for the dehydrocoupling of the non-cyclic boranes, dicyclohexylborane and thexylborane, with amines under mild conditions. The reactions afforded the corresponding aminoboranes in high yields with good functional group tolerance. The stoichiometric reaction of scandium alkyl with amine led to the isolation of a scandium amide complex, which was shown to be an active species during the catalysis. Although a borane-coordinated scandium hydride was also obtained from the stoichiometric experiment, it was not involved in the catalytic cycle. In addition, kinetic studies provided insight into this intermol. dehydrogenation reaction. This study involved multiple reactions and reactants, such as 2-Methoxyethylamine (cas: 109-85-3SDS of cas: 109-85-3).
2-Methoxyethylamine (cas: 109-85-3) belongs to ethers. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.SDS of cas: 109-85-3
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem