Mortazavi, Saeideh-Sadat published the artcileA new Bronsted acid MIL-101(Cr) catalyst by tandem post-functionalization; synthesis and its catalytic application, Quality Control of 1589-47-5, the publication is Applied Organometallic Chemistry (2020), 34(8), e5717, database is CAplus.
A new heterogeneous Bronsted solid acid catalyst was prepared by tandem post-functionalization of MIL-101(Cr) and utilized for acetic acid esterification and alcoholysis of epoxides under solvent-free conditions. First, MIL-101(Cr) was functionalized with pyrazine to achieve MIL-101(Cr)-Pyz. Afterwards, the nucleophilic reaction of MIL-101(Cr)-Pyz with 1,3-propane sultone and next acidification with diluted sulfuric acid gave MIL-101(Cr)-Pyz-RSO3H Bronsted solid acid catalyst. Various characterization methods such as Fourier transformation IR (FT-IR) spectroscopy, X-ray diffraction (XRD), elemental anal. (CHNS), XPS, SEM (SEM), energy-dispersive X-ray (EDX) spectroscopy, thermal anal. (TGA/DTA), acid-base titration, and N2 adsorption/desorption anal. were employed to fully characterize the prepared catalyst. The catalyst showed high activity compared to unmodified MIL-101(Cr) in both catalytic acetic acid esterification and alcoholysis of epoxides. It can also be readily isolated from the reaction mixture and reused three times without major decrease in its activity.
Applied Organometallic Chemistry published new progress about 1589-47-5. 1589-47-5 belongs to ethers-buliding-blocks, auxiliary class Aliphatic hydrocarbon chain,Alcohol,Ether, name is 2-Methoxypropan-1-ol, and the molecular formula is C4H10O2, Quality Control of 1589-47-5.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem