Controlled Alcohol-Carbonyl Interconversion by Nickel Catalysis was written by Maekawa, Takehisa;Sekizawa, Hiromi;Itami, Ken-Ichiro. And the article was included in Angewandte Chemie, International Edition in 2011.Application In Synthesis of 2-(3-Methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborinane The following contents are mentioned in the article:
The one-pot reaction of primary alcs. with arylneopentylboronates in presence of [Ni(cod)2] and 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene hydrochloride to give secondary and tertiary alcs. is reported. This study involved multiple reactions and reactants, such as 2-(3-Methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborinane (cas: 1003858-50-1Application In Synthesis of 2-(3-Methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborinane).
2-(3-Methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborinane (cas: 1003858-50-1) belongs to ethers. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Esters contain a carbonyl center, which gives rise to 120° C–C–O and O–C–O angles. Unlike amides, esters are structurally flexible functional groups because rotation about the C–O–C bonds has a low barrier. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Application In Synthesis of 2-(3-Methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborinane
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem