Synthesis of Aryl Perfluorocyclopropyl Ethers via [2 + 1] Cyclopropanation Using TMSCF2Br Reagent was written by Liu, Ran;Hu, Jinbo. And the article was included in Organic Letters in 2022.Recommanded Product: 4-Benzyloxyphenol The following contents are mentioned in the article:
Aryl perfluorocyclopropyl ethers have been synthesized for the first time by [2 + 1] cyclopropanation between aryl trifluorovinyl ethers and a com. available TMSCF2Br reagent. This cycloaddition reaction between two fluorine-containing reactants proceeds smoothly in toluene at 120°C in the presence of a catalytic amount of n-Bu4NBr, and the reaction tolerates a variety of functional groups. A wide range of aryl trifluorovinyl ethers, easily accessible from phenols, were successfully transformed to aryl perfluorocyclopropyl ethers. This study involved multiple reactions and reactants, such as 4-Benzyloxyphenol (cas: 103-16-2Recommanded Product: 4-Benzyloxyphenol).
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Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem