Nickel-Catalyzed Decarbonylative Borylation of Amides: Evidence for Acyl C-N Bond Activation was written by Hu, Jiefeng;Zhao, Yue;Liu, Jingjing;Zhang, Yemin;Shi, Zhuangzhi. And the article was included in Angewandte Chemie, International Edition in 2016.Electric Literature of C12H17BO3 The following contents are mentioned in the article:
A Ni/N-heterocyclic carbene catalytic system was established for decarbonylative borylation of amides with B2nep2 (nep = neopentylglycolato) by C-N bond activation. This transformation shows good functional-group compatibility and can serve as a powerful synthetic tool for late-stage borylation of amide groups in complex compounds More importantly, as a key intermediate, the structure of an acyl Ni complex was 1st confirmed by x-ray anal. Also, the decarbonylative process was also observed These findings confirm the key mechanistic features of the acyl C-N bond activation process. This study involved multiple reactions and reactants, such as 2-(3-Methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborinane (cas: 1003858-50-1Electric Literature of C12H17BO3).
2-(3-Methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborinane (cas: 1003858-50-1) belongs to ethers. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Electric Literature of C12H17BO3
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem