Solvation sheath reorganization enables divalent metal batteries with fast interfacial charge transfer kinetics was written by Hou, Singyuk;Ji, Xiao;Gaskell, Karen;Wang, Peng-fei;Wang, Luning;Xu, Jijian;Sun, Ruimin;Borodin, Oleg;Wang, Chunsheng. And the article was included in Science (Washington, DC, United States) in 2021.Electric Literature of C3H9NO The following contents are mentioned in the article:
Rechargeable magnesium and calcium metal batteries (RMBs and RCBs) are promising alternatives to lithium-ion batteries because of the high crustal abundance and capacity of magnesium and calcium. Yet, they are plagued by sluggish kinetics and parasitic reactions. We found a family of methoxyethyl-amine chelants that greatly promote interfacial charge transfer kinetics and suppress side reactions on both the cathode and metal anode through solvation sheath reorganization, thus enabling stable and highly reversible cycling of the RMB and RCB full cells with energy densities of 412 and 471 W-hours per kg, resp. This work provides a versatile electrolyte design strategy for divalent metal batteries. This study involved multiple reactions and reactants, such as 2-Methoxyethylamine (cas: 109-85-3Electric Literature of C3H9NO).
2-Methoxyethylamine (cas: 109-85-3) belongs to ethers. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Esterification is the general name for a chemical reaction in which two reactants (typically an alcohol and an acid) form an ester as the reaction product. Esters are common in organic chemistry and biological materials.Electric Literature of C3H9NO
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem