Copper/Nitroxyl-Catalyzed Synthesis of Pyrroles by Oxidative Coupling of Diols and Primary Amines at Room Temperature was written by Fu, Weiru;Zhu, Lina;Tan, Shangzhi;Zhao, Zhengjia;Yu, Xiangzhu;Wang, Lianyue. And the article was included in Journal of Organic Chemistry in 2022.Recommanded Product: 2-Methoxyethylamine The following contents are mentioned in the article:
Cu/ABNO-catalyzed aerobic oxidative coupling of diols and primary amines to access N-substituted pyrroles I [R = n-hexyl, n-Bu, Bn, etc.; R1 = H, Me, Ph] was highlighted (ABNO = 9-azabicyclo[3.3.1]nonane-N-oxyl). The reaction proceeded at room temperature with O2 balloon as the oxidant using com. available materials as the substrates and catalysts. The catalyst system was characterized by a broad range of substrates and good tolerance to sensitive functional groups. The experiment of gram-scale proved its practicability. This study involved multiple reactions and reactants, such as 2-Methoxyethylamine (cas: 109-85-3Recommanded Product: 2-Methoxyethylamine).
2-Methoxyethylamine (cas: 109-85-3) belongs to ethers. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Recommanded Product: 2-Methoxyethylamine
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem