Chiral discrimination of 2-heptylaminium salt by planar-chiral monohydroxy-functionalized pillar[5]arenes was written by Al-Azemi, Talal F.;Vinodh, Mickey;Alipour, Fatemeh H.;Mohamod, Abdirahman A.. And the article was included in Organic Chemistry Frontiers in 2019.Computed Properties of C13H12O2 The following contents are mentioned in the article:
The synthesis of a planar-chiral monohydroxy-functionalized pillar[5]arene amenable to a wide variety of chem. modifications was reported. Chiral resolution was performed using derivatization with Mosher’s acid chloride (S)-(+)-α-methoxy-α-trifluoromethylphenylacetyl chloride ((S)-(+)-MTPA-Cl), and the absolute configurations of the thus obtained MTPA ester-functionalized pillar[5]arenes were determined by single-crystal X-ray diffraction. Finally, the effect of hydroxy groups on the temperature-dependent rotational movement of pillar[5]arene units was investigated by chiral HPLC and its application as a chiral receptor for alkyl aminium salts was demonstrated. This study involved multiple reactions and reactants, such as 4-Benzyloxyphenol (cas: 103-16-2Computed Properties of C13H12O2).
4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits, including apples, durians, pears, bananas, pineapples, and strawberries. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Computed Properties of C13H12O2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem