Selective organic phase hydrodeoxygenation of typical phenolic monomers and two lignin oils over highly active Pd/Hβ catalyst for high-grade bio-fuel production was written by Hu, Lin;Wei, Xian-Yong;Xu, Mei-Ling;Kang, Yu-Hong;Guo, Xian-Hou;Zhang, Feng-Bin;Zong, Zhi-Min;Bai, Hong-Cun. And the article was included in Journal of Environmental Chemical Engineering in 2021.Product Details of 103-16-2 The following contents are mentioned in the article:
The selective hydrodeoxygenation (HDO) of lignin-derived bio-oil still meets the great challenges due to its complex oxygenated organic component. In this research, first time, Pd-based zeolite catalysts were prepared by the modified deposition-precipitation (DP) method for the HDO conversion of guaiacol. Notably, for the same Si/Al ratio of zeolite, Pd2%/Hβ catalyst showed the higher catalytic activity on the HDO of guaiacol than that Pd2%/M and Pd2%/HZSM-5 catalyst, which mainly originated from the synergetic effect between metal nanoparticles size and acid sites of catalyst. As one of typical phenolic monomers, guaiacol can be converted into high yield of hydrocarbons under the condition of 220°C, 3 MPa H2, and 4 h in n-hexane over Pd2%/Hβ (DP) catalyst. This highly active catalyst exhibited the good recyclability in the HDO conversion of guaiacol. In addition, other typical phenolic monomers can be converted into high yield of hydrocarbons over this highly active catalyst. Considering this, after HDO upgrading, real lignin oil (RLO) can be converted into high yield of hydrocarbons with the carbon number (CN) in range of C7-C15. This work highlighted that the depolymerization monomers from lignin can be further upgraded by this high active catalyst through HDO to obtain jet hydrocarbons fuel. This study involved multiple reactions and reactants, such as 4-Benzyloxyphenol (cas: 103-16-2Product Details of 103-16-2).
4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Product Details of 103-16-2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem