Insights into the electrochemical degradation of phenolic lignin model compounds in a protic ionic liquid-water system was written by Liu, Guangyong;Wang, Qian;Yan, Dongxia;Zhang, Yaqin;Wang, Chenlu;Liang, Shijing;Jiang, Lilong;He, Hongyan. And the article was included in Green Chemistry in 2021.Recommanded Product: 4-Benzyloxyphenol The following contents are mentioned in the article:
Cleavage of aryl ether (Caryl-O) bonds is crucial for the conversion and value-added utilization of lignin and its derivatives, but remains extremely challenging under mild conditions due to strong Caryl-O linkages. In this study, the Caryl-O bond breaking is achieved through electrocatalytic oxidation of four phenolic lignin model compounds with typical Caryl-O bonds, i.e., 4-ethoxyphenol (EP), 4-phenoxyphenol (PP), p-benzyloxyphenol (PBP), and 2-(2-phenylethoxy)phenol (2-PEP), in a protic ionic liquid [BSO3Hmim][OTf]-H2O electrolyte, and the electrocatalytic oxidation mechanism is also fully explored. The effects of H2O on the viscosity and conductivity of the [BSO3Hmim][OTf] ionic liquid system, as well as the solubility and diffusion coefficients of O2 and the four lignin substrates, are investigated to optimize the optimal ratio of the electrolyte system composed of [BSO3Hmim][OTf] and H2O. Electrochem. oxidation-reduction behaviors of the four lignin substrates in the [BSO3Hmim][OTf]-H2O system and the effect of O2 and N2 atmospheres on degradation are studied in detail by using cyclic voltammetry (CV) curves. Finally, by combining the anal. of degradation products with isotope labeling experiments, the C-O bond cleavage mechanism is obtained, which mainly involves direct and indirect oxidation Specifically, under a N2 atmosphere, the substrates are oxidized directly on the RuO2-IrO2/Ti mesh electrode through Caryl-O bond splitting to form quinone and carbonium ions, while under an O2 atmosphere, apart from the direct oxidation on the electrode, indirect oxidation of the lignin substrates also occurs through in situ generated H2O2. This study may provide some insight into developing effective strategies for efficient utilization of lignin under mild conditions. This study involved multiple reactions and reactants, such as 4-Benzyloxyphenol (cas: 103-16-2Recommanded Product: 4-Benzyloxyphenol).
4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Recommanded Product: 4-Benzyloxyphenol
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem