Tota, Arianna; Zenzola, Marina; Chawner, Stephen J.; John-Campbell, Sahra St; Carlucci, Claudia; Romanazzi, Giuseppe; Degennaro, Leonardo; Bull, James A.; Luisi, Renzo published an article in 2017, the title of the article was Synthesis of NH-sulfoximines from sulfides by chemoselective one-pot N- and O-transfers.Electric Literature of 53136-21-3 And the article contains the following content:
Direct synthesis of NH-sulfoximines from sulfides were achieved through O and NH transfer in the same reaction, occurring with complete selectivity. The reaction was mediated by bisacetoxyiodobenzene under simple conditions and employs inexpensive N-sources. Preliminary studies indicated that NH-transfer was likely to be first, followed by oxidation, but the reaction proceedes successfully in either order. A wide range of functional groups and biol. relevant compounds were tolerated. The use of AcO15NH4 affords 15N-labeled compounds The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Electric Literature of 53136-21-3
The Article related to sulfide preparation ammonium carbamate bisacetoxyiodobenzene oxidation imination, sulfoximine chemoselective preparation, General Organic Chemistry: Synthetic Methods and other aspects.Electric Literature of 53136-21-3
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