On August 19, 2022, Ritu; Das, Saikat; Tian, Ya-Ming; Karl, Tobias; Jain, Nidhi; Konig, Burkhard published an article.Electric Literature of 93-04-9 The title of the article was Photocatalyzed Dehydrogenation of Aliphatic N-Heterocycles Releasing Dihydrogen. And the article contained the following:
Author’s report the iridium-nickel dual photocatalytic acceptorless and redox neutral dehydrogenation of aliphatic heterocycles yielding cyclic alkenes without overoxidn. at room temperature Excitation of the iridium photocatalyst initiates the formation of a nickel hydride intermediate that yields alkenes and H2 via β-hydride elimination. The reaction proceeds regioselectively and the scope was demonstrated by the synthesis of 12 biol. relevant mols. and drugs. In addition, com. and easily available N-heterocyclic alkane starting materials were converted into functionalized alkenes of high synthetic and com. value using the method. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).Electric Literature of 93-04-9
The Article related to cyclic enamide enecarbamate preparation regioselective photochem, aliphatic heterocycle dehydrogenation hydride elimination iridium nickel catalyst, General Organic Chemistry: Synthetic Methods and other aspects.Electric Literature of 93-04-9
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