On December 31, 2009, Khodaei, Mohammad Mehdi; Bahrami, Kiumars; Tirandaz, Yeganeh published an article.COA of Formula: C13H11BrS The title of the article was POCl3 as a catalytic activator for H2O2 activation in selective sulfide oxidation. And the article contained the following:
Various types of sulfides are selectively oxidized to sulfoxides in excellent yields using 30% aqueous hydrogen peroxide as an oxidant in the presence of POCl3 in ethanol at 50°. It is noteworthy that functional groups remain unaffected and only the sulfur atom is selectively oxidized. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).COA of Formula: C13H11BrS
The Article related to sulfide selective oxidation hydrogen peroxide oxidant phosphoryl chloride catalyst, sulfoxide preparation, General Organic Chemistry: Synthetic Methods and other aspects.COA of Formula: C13H11BrS
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem