Hamby, Taylor B.; LaLama, Matthew J.; Sevov, Christo S. published an article in 2022, the title of the article was Controlling Ni redox states by dynamic ligand exchange for electroreductive C(sp3)-C(sp2) coupling.Related Products of 93-04-9 And the article contains the following content:
Cross-electrophile coupling (XEC) reactions of aryl and alkyl electrophiles are appealing but limited to specific substrate classes. Here, electroreductive XEC of previously incompatible electrophiles including tertiary alkyl bromides, aryl chlorides, and aryl/vinyl triflates are reported. The reactions rely on the merger of an electrochem. active complex that selectively reacts with alkyl bromides through 1e- processes and an electrochem. inactive Ni0(phosphine) complex that selectively reacts with aryl electrophiles through 2e- processes. Accessing Ni0(phosphine) intermediates is critical to the strategy but is often challenging. Here, a previously unknown pathway for electrochem. generating these key complexes at mild potentials through a choreographed series of ligand-exchange reactions has been uncovered. The mild methodol. is applied to the alkylation of a range of substrates including natural products and pharmaceuticals. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).Related Products of 93-04-9
The Article related to aryl vinyl halide triflate electroreductive coupling alkyl bromide nickel, General Organic Chemistry: Synthetic Methods and other aspects.Related Products of 93-04-9
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