On May 4, 2001, Bravo, Anna; Dordi, Barbara; Fontana, Francesca; Minisci, Francesco published an article.Application of 53136-21-3 The title of the article was Oxidation of Organic Sulfides by Br2 and H2O2. Electrophilic and Free-Radical Processes. And the article contained the following:
The bromine-catalyzed oxidation of sulfides with hydrogen peroxide was studied. Diaryl sulfides do not react with hydrogen peroxide and a catalytic amount of bromine; the latter is consumed by electrophilic aromatic substitution and no further reaction occurs. Dibenzyl sulfide reacts with hydrogen peroxide and a catalytic amount of bromide leading mainly to dibenzyl sulfoxide and minor amounts of benzyl bromide, benzenemethanesulfonic acid, benzyl alc. and benzaldehyde. Benzyl bromide and benzenemethanesulfonic acid were obtained in almost quant. yield by using stoichiometric amounts of bromine in the absence of hydrogen peroxide. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Application of 53136-21-3
The Article related to sulfide oxidation bromine peroxide, sulfoxide preparation, General Organic Chemistry: Synthetic Methods and other aspects.Application of 53136-21-3
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