On July 22, 2022, Zhou, Jun; Jiang, Bingyao; Zhao, Zhengyu; Shibata, Norio published an article.COA of Formula: C7H7FO The title of the article was Etherification of Fluoroarenes with Alkoxyboronic Acid Pinacol Esters via C-F Bond Cleavage. And the article contained the following:
Potassium-base-mediated defluoroetherification of aryl and heteroaryl fluorides with alkoxyboronic acid pinacol esters under transition-metal-free conditions is reported. This protocol efficiently and safely provides a wide variety of aryl ethers in high yields without using metal catalysts, specific ligands, and harsh conditions to selectively forge Csp2-O bonds via the Csp2-F cleavage. This method can be applied to the late-stage etherification of structurally complex Csp2-fluorides and bioactive alcs., such as å°?estradiol, calciferol, and tocopherol. The experimental process involved the reaction of 1-Fluoro-2-methoxybenzene(cas: 321-28-8).COA of Formula: C7H7FO
The Article related to alkyl aryl ether preparation, fluoroarene alkoxyboronic acid pinacol ester etherification bond cleavage, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Esters, Acyl Peroxides, Acyl Halides and other aspects.COA of Formula: C7H7FO
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem