On November 5, 2021, Neil, Baptiste; Lucien, Franck; Fensterbank, Louis; Chauvier, Clement published an article.Product Details of 321-28-8 The title of the article was Transition-Metal-Free Silylation of Unactivated C(sp2)-H Bonds with tert-Butyl-Substituted Silyldiazenes. And the article contained the following:
Aromatic organosilanes bearing C(sp2)-Si bonds found increasing applications across the chem. science, yet are mostly produced by atom-uneconomical stoichiometric procedures. Catalytic alternatives using hydrosilanes as Si sources also were described, but they display unfavorable thermodn. and are mostly based on expensive catalytic systems, often derived from noble metals, or lack generality. Herein, the authors describe the use of an alternative Si source, the tert-butyl-substituted silyldiazenes (tBu-N:N-SiR3), that are readily accessible from com. available precursors and whose structure enables the C(sp2)-H bond silylation of unactivated heteroaryl and aryl compounds under ambient, transition-metal-free catalytic conditions. The experimental process involved the reaction of 1-Fluoro-2-methoxybenzene(cas: 321-28-8).Product Details of 321-28-8
The Article related to unactivated carbon hydrogen bond heteroaryl aromatic compound silylation silyldiazene, aromatic organosilane preparation, heteroaryl silane preparation, Organometallic and Organometalloidal Compounds: Silicon Compounds and other aspects.Product Details of 321-28-8
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Ether | (C2H5)2O – PubChem