On May 21, 2021, Kuleshova, Olena; Asako, Sobi; Ilies, Laurean published an article.Computed Properties of 321-28-8 The title of the article was Ligand-Enabled, Iridium-Catalyzed ortho-Borylation of Fluoroarenes. And the article contained the following:
A terpyridine derivative and an iridium complex catalyze the C-H borylation of a stoichiometric amount of a fluoroarene with high ortho-selectivity and tolerance of functional groups such as bromide, chloride, ester, ketone, amine, and in situ-borylated hydroxyl. Complex drug mols. such as haloperidol can be selectively borylated ortho to the F atom. The terpyridine ligand undergoes rollover cyclometalation to produce an N,N,C-coordinated iridium complex, which may either selectively borylate the fluoroarene by itself or undergo reductive elimination to produce a borylated ligand. The experimental process involved the reaction of 1-Fluoro-2-methoxybenzene(cas: 321-28-8).Computed Properties of 321-28-8
The Article related to fluoroarene directed ortho borylation iridium catalyst preparation arylboronic ester, terpyridine iridium complex catalyst directed ortho borylation aryl fluoride, Organometallic and Organometalloidal Compounds: Boron Compounds and other aspects.Computed Properties of 321-28-8
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem