On May 31, 2018, Zhou, Fan; Zhang, Jingshuang; Fu, Tianyi; Bai, Peng; Guo, Xianghai published an article.Recommanded Product: 321-28-8 The title of the article was Theoretical study on complexes and reactions of boron isotopic exchange separation with fluorinated anisoles as novel donors. And the article contained the following:
Semi-empirical and ab initio d.-functional theory (DFT) methods were evaluated for the description of isotope exchange reactions to produce enriched 10B species. We found that DFT calculations using M06-2X/6-311+G(3d,2p) functional and basis sets in combination with the SMD implicit solvation model were able to correctly predict the performance of various anisole-derived donor mols. We confirmed that fluorination results in greatly increased separation factors, and successfully identified the o- and 2,4-difluorinated anisole as superior donors for chem. exchange distillation These findings provide the basis for an efficient approach to rapidly screen and design new donor species. The experimental process involved the reaction of 1-Fluoro-2-methoxybenzene(cas: 321-28-8).Recommanded Product: 321-28-8
The Article related to anisole borontrifluoride complexation isotope exchange reaction enthalpy potential barrier, Physical Organic Chemistry: Addition, Elimination, and Substitution Reactions and other aspects.Recommanded Product: 321-28-8
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem