On May 15, 2009, Roviello, Antonio; Borbone, Fabio; Carella, Antonio; Diana, Rosita; Roviello, Giuseppina; Panunzi, Barbara; Ambrosio, Antonio; Maddalena, Pasqualino published an article.Application In Synthesis of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene The title of the article was High quantum yield photoluminescence of new polyamides containing oligo-PPV amino derivatives and related oligomers. And the article contained the following:
The synthesis and the chem. phys. characterization of new photoluminescent (PL) chromophores and polymers are reported. Chromophores (oligo-PPV sym. derivatives ending with amino groups) are strong blue emitters with a PL quantum yield of ∼70% in dioxane solution They have been used to prepare polyamides by reaction with aliphatic acyl dichlorides in which emitting and non emitting units are alternated. PL properties of the synthesized polyamides have been evaluated in solution and reveal a strong blue emission (PL quantum yield ∼60%), to increase the solubility of these systems, oligomers have been purposely prepared and then characterized. They show a peculiar white emission when excited in DMF solution; to get insight into this interesting behavior, asym. monoacetylated chromophores have been prepared as model compounds for the chromophoric end groups of the polyamide chains. The emission spectra of these compounds reveal a broad excimeric yellow emission which is responsible, along with the blue emission of the inner chromophoric units, of the overall white emission of the oligomers. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 2677-2689, 2009. The experimental process involved the reaction of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene(cas: 146370-51-6).Application In Synthesis of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene
The Article related to phenylenevinylene fragment polyamide dodecanoyl suberoyl synthesis photoluminescence fluorescence, Chemistry of Synthetic High Polymers: Organic Condensation and Step Polymerization and other aspects.Application In Synthesis of 1-((2-Ethylhexyl)oxy)-4-methoxybenzene
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