Pereira, Raul; Wolstenhulme, Jamie; Sandford, Graham; Claridge, Timothy D. W.; Gouverneur, Veronique; Cvengros, Jan published an article in 2016, the title of the article was Synthesis and characterization of a novel N-F reagent derived from the ethano-Tröger’s base: 1JFN coupling constants as a signature for the N-F bond.Application of 321-28-8 And the article contains the following content:
Methylation of 2,8-dimethyl-6H,12H-5,11-ethanodibenzo[b,f][1,5]-diazocine (ethano-Troddoger’s base) with Me iodide followed by ion metathesis and fluorination with N-fluoro-2,3,4,5,6-pentachloropyridinium triflate affords a new electrophilic N-F reagent, that is more reactive than Selectfluor. 2D 19F-15N HMQC experiments provide 1JNF coupling constants which are diagnostic for the N-F functional group. The experimental process involved the reaction of 1-Fluoro-2-methoxybenzene(cas: 321-28-8).Application of 321-28-8
The Article related to electrophile preparation dimethylethanodibenzodiazocine methylation metathesis fluorination hmqc coupling constant, Physical Organic Chemistry: Addition, Elimination, and Substitution Reactions and other aspects.Application of 321-28-8
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem