On September 25, 2006, Kelly, Padraig; Lawrence, Simon E.; Maguire, Anita R. published an article.Related Products of 53136-21-3 The title of the article was Asymmetric synthesis of aryl benzyl sulfoxides by vanadium-catalysed oxidation: a combination of enantioselective sulfide oxidation and kinetic resolution in sulfoxide oxidation. And the article contained the following:
Enantioselective vanadium-catalyzed oxidation of aryl benzyl sulfides R1SCH2R2 (R1 = Ph, 4-MeC6H4, 4-BrC6H4; R2 = Ph, 4-FC6H4, 4-ClC6H4, 4-MeC6H4, 2-MeOC6H4, 4-MeOC6H4) using Bolm’s procedure is accompanied by kinetic resolution in the oxidation of the resulting sulfoxides, resulting in formation of chiral sulfoxides typically with >90% ee along with the corresponding sulfones. The effect of a ligand, solvent and reaction conditions are discussed in detail. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Related Products of 53136-21-3
The Article related to sulfoxide aryl benzyl asym synthesis, sulfide aryl benzyl enantioselective oxidation kinetic resolution vanadium catalyst, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Sulfoxides and Sulfones and other aspects.Related Products of 53136-21-3
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