Coulomb, Julien; Certal, Victor; Larraufie, Marie-Helene; Ollivier, Cyril; Corbet, Jean-Pierre; Mignani, Gerard; Fensterbank, Louis; Lacote, Emmanuel; Malacria, Max published an article in 2009, the title of the article was Intramolecular Homolytic Substitution of Sulfinates and Sulfinamides.Formula: C8H10BrNO And the article contains the following content:
A general and efficient method for the synthesis of cyclic sulfinates and sulfinamides based on intramol. homolytic substitution (SHi) at the sulfur atom by aryl or alkyl radicals is described. Both alkyl and benzofused compounds can be accessed directly from easily prepared acyclic precursors. Enantiomerically enriched sulfur-based heterocycles were formed through an SHi process with inversion of configuration at the sulfur atom. Cyclization of prochiral radicals proceeded with varying stereochem. outcomes, depending on the size of the incoming radical. 2-Pyridyl and 2-quinolyl radicals led to biaryl compounds, which result from attack onto the ortho position of the arylsulfinate rather than a thiophilic substitution. The experimental process involved the reaction of (2-Bromo-5-methoxyphenyl)methanamine(cas: 887581-09-1).Formula: C8H10BrNO
The Article related to intramol homolytic substitution sulfinate sulfinamide oxathiolane isothiazolidine preparation, Heterocyclic Compounds (More Than One Hetero Atom): Dioxoles, Oxathioles, Dithioles and other aspects.Formula: C8H10BrNO
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem