On July 22, 2015, Capozzi, Maria Annunziata M.; Terraneo, Giancarlo; Cavallo, Gabriella; Cardellicchio, Cosimo published an article.Application of 53136-21-3 The title of the article was The search for exceptions in the highly enantioselective titanium catalysed oxidation of aryl benzyl sulfides. And the article contained the following:
After the discovery of a few cases of lower enantioselectivity in the oxidation of aryl benzyl sulfides with hydroperoxides in the presence of a complex between titanium isopropoxide and (S, S)-hydrobenzoin, a screening of the oxidation of new substrates that are related to the structures that gave low ee values, was performed. From this screening, we confirmed that only a few sulfides remain as exceptions within a framework of exceptionally high stereoselectivity of the oxidation reaction. Moreover, the exceptions are clearly identified and are connected to particular coordinating moieties present on the aryl groups. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Application of 53136-21-3
The Article related to sulfide aryl benzyl titanium chiral hydrobenzoin stereoselective oxidation catalyst, sulfoxide stereoselective preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Sulfoxides and Sulfones and other aspects.Application of 53136-21-3
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