On September 30, 2021, Rawat, Vishal Kumar; Higashida, Kosuke; Sawamura, Masaya published an article.Computed Properties of 93-04-9 The title of the article was Nickel-Catalyzed Homocoupling of Aryl Ethers with Magnesium Anthracene Reductant. And the article contained the following:
Nickel-catalyzed reductive homocoupling of aryl ethers has been achieved with Mg(anthracene)(thf)3 as a readily available low-cost reductant. DFT calculations provided a rationale for the specific efficiency of the diorganomagnesium-type two-electron reducing agent. The calculations show that the dianionic anthracene-9,10-diyl ligand reduces the two aryl ether substrates, resulting in the homocoupling reaction through supply of electrons to the Ni-Mg bimetallic system to form organomagnesium nickel(0)-ate complexes, which cause two sequential C-O bond cleavage reactions. The calculations also showed cooperative actions of Lewis acidic magnesium atoms and electron-rich nickel atoms in the C-O cleavage reactions. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).Computed Properties of 93-04-9
The Article related to aryl ether reductive homocoupling nickel catalyst magnesium anthracene reductant, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Hydrocarbons (Saturated and Unsaturated Side Chains) and other aspects.Computed Properties of 93-04-9
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem