Panja, Subir; Ahsan, Salman; Pal, Tanay; Kolb, Simon; Ali, Wajid; Sharma, Sulekha; Das, Chandan; Grover, Jagrit; Dutta, Arnab; Werz, Daniel B.; Paul, Amit; Maiti, Debabrata published an article in 2022, the title of the article was Non-directed Pd-catalysed electrooxidative olefination of arenes.Synthetic Route of 91-16-7 And the article contains the following content:
The Fujiwara-Moritani reaction is a powerful tool for the olefination of arenes by Pd-catalyzed C-H activation. However, the need for superstoichiometric amounts of toxic chem. oxidants makes the reaction unattractive from an environmental and atom-economical view. Herein, authors report the first non-directed and regioselective olefination of simple arenes via an electrooxidative Fujiwara-Moritani reaction. The versatility of this operator-friendly approach was demonstrated by a broad substrate scope which includes arenes, heteroarenes and a variety of olefins. Electroanal. studies suggest the involvement of a Pd(II)/Pd(IV) catalytic cycle via a Pd(III) intermediate. The experimental process involved the reaction of 1,2-Dimethoxybenzene(cas: 91-16-7).Synthetic Route of 91-16-7
The Article related to arene alpha beta unsaturated ester regioselective olefination, non directed palladium catalyst electrooxidative fujiwara moritani, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Hydrocarbons (Saturated and Unsaturated Side Chains) and other aspects.Synthetic Route of 91-16-7
Referemce:
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