On September 16, 2022, Pan, Yue; Liu, Zhengyi; Zou, Peng; Chen, Yali; Chen, Yiyun published an article.Category: ethers-buliding-blocks The title of the article was Hypervalent Iodine Reagents Enable C(sp2)-H Amidation of (Hetero)arenes with Iminophenylacetic Acids. And the article contained the following:
The sulfonamidyl (hetero)arenes synthesis by the C(sp2)-H amidation from bench-stable amidyl-iminophenylacetic acids was reported. The hypervalent iodine reagents covalently activated iminophenylacetic acids for the facile sulfonamidyl radical generation under mild photocatalytic oxidative conditions. Diversified indoles, pyrroles, imidazopyridines and fused arenes underwent the C(sp2)-H amidation with excellent chemoselectivity and regioselectivity. This reaction performed well under neutral aqueous conditions with potential biol. applications. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).Category: ethers-buliding-blocks
The Article related to amidyl iminophenylacetic acid hetero arene ruthenium catalyst photochem sulfonamidation, hetero aryl benzene sulfonamide preparation chemoselective regioselective, Heterocyclic Compounds (One Hetero Atom): Indoles, Indolizines, Carbazoles, and Other Arenopyrroles and other aspects.Category: ethers-buliding-blocks
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