On January 19, 2022, Jacob, Nicolas; Zaid, Yassir; Oliveira, Joao C. A.; Ackermann, Lutz; Wencel-Delord, Joanna published an article.Recommanded Product: 93-04-9 The title of the article was Cobalt-Catalyzed Enantioselective C-H Arylation of Indoles. And the article contained the following:
Herein, the unprecedented earth-abundant 3D-metal-catalyzed atroposelective direct arylation was reported, furnishing rare atropoisomeric C2-arylated indoles. Kinetic studies and DFT computation revealed an uncommon mechanism for this asym. transformation, with the oxidative addition being the rate- and enantio-determining step. Excellent stereoselectivities were reached (up to 96% ee), while using an unusual N-heterocyclic carbene-ligand bearing essential remote substituent. Attractive dispersion interactions along with pos. C-H—π interactions exerted by the ligand were identified as key factors to guarante the excellent enantioselection. The experimental process involved the reaction of 2-Methoxynaphthalene(cas: 93-04-9).Recommanded Product: 93-04-9
The Article related to methoxyphenyl indole methanimine chloronaphthalene cobalt catalyst enantioselective arylation, naphthalenyl indole carbaldehyde preparation, Heterocyclic Compounds (One Hetero Atom): Indoles, Indolizines, Carbazoles, and Other Arenopyrroles and other aspects.Recommanded Product: 93-04-9
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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem