On March 6, 2020, Dhandabani, Ganesh Kumar; Shih, Chia-Ling; Wang, Jeh-Jeng published an article.Related Products of 157869-15-3 The title of the article was Acid-Promoted Intramolecular Decarbonylative Coupling Reactions of Unstrained Ketones: A Modular Approach to Synthesis of Acridines and Diaryl Ketones. And the article contained the following:
Herein, Lewis acid- or Bronsted acid-promoted intramol. C(sp2)-C(sp2) bond cleavage and a novel C(sp2)-C(sp2) bond-forming cascade reaction to synthesize the acridine motif is reported. The metal-free oxidation of the alkyne motif generated the in situ ketone group extracted via a decarbonylation reaction. The mechanistic studies revealed that the electrophilic N-iodo species triggered key decarbonylation reactions via consecutive dearomatization/aromatization reactions. In addition, this acid-promoted C-C bond activation system with internal alkynes to synthesize bis(heteroaryl) ketones is exploited. The experimental process involved the reaction of 2-((4-Methoxyphenyl)ethynyl)aniline(cas: 157869-15-3).Related Products of 157869-15-3
The Article related to acridine diaryl ketone preparation, ketone alkynylaniline intramol decarbonylative coupling reaction, internal alkyne bond activation, Heterocyclic Compounds (One Hetero Atom): Other Areno- and Diarenopyridines (Acridines, Quinolizines, etc.) and other aspects.Related Products of 157869-15-3
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem