On July 19, 2019, Chen, Yang; Qi, Hongyi; Chen, Ning; Ren, Demin; Xu, Jiaxi; Yang, Zhanhui published an article.Recommanded Product: Benzyl(4-bromophenyl)sulfane The title of the article was Fluorium-Initiated Dealkylative Cyanation of Thioethers to Thiocyanates. And the article contained the following:
Thioethers are converted to thiocyanates via fluorium-initiated dealkylative cyanation. Selectfluor is used as the oxidant, and trimethylsilyl cyanide is used as the cyanation reagent. The well-streamlined procedure is user-friendly, operationally simple, and step-economical. The current mechanistic studies show that the sulfur radical cation and cyano radical are both involved. They combine to deliver cyanosulfonium, an intermediate toward thiocyanate after dealkylation. Alternatively, a nucleophilic mechanism is also possible. This dealkylative cyanation is also efficient in synthesizing thiocyanates with strongly electrophilic functionalities. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Recommanded Product: Benzyl(4-bromophenyl)sulfane
The Article related to thioether dealkylative cyanation, thiocyanate preparation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Ethers, Sulfides, and The Corresponding Onium Compounds and other aspects.Recommanded Product: Benzyl(4-bromophenyl)sulfane
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem