Capozzi, Maria Annunziata M.; Centrone, Caterina; Fracchiolla, Giuseppe; Naso, Francesco; Cardellicchio, Cosimo published an article in 2011, the title of the article was A Study of Factors Affecting Enantioselectivity in the Oxidation of Aryl Benzyl Sulfides in the Presence of Chiral Titanium Catalysts.Name: Benzyl(4-bromophenyl)sulfane And the article contains the following content:
A series of experiments was performed to test a theor. model that we have recently proposed to explain the highly enantioselective oxidation of aryl benzyl sulfides with tert-Bu hydroperoxide in the presence of a complex between titanium and (S,S)- or (R,R)-hydrobenzoin. The studied variations involved the sulfides, the ligands, and the order of addition of reactants. The reaction path predicted by our model was confirmed in every experiment In particular, aryl benzyl sulfides behaved as the ideal substrate for this type of asym. oxidation, which yields synthetically useful, enantiopure aryl benzyl sulfoxides in a straightforward manner. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Name: Benzyl(4-bromophenyl)sulfane
The Article related to enantioselective oxidation aryl benzyl sulfide chiral titanium catalyst, Physical Organic Chemistry: Stereochemistry and Stereochemical Relationships, Including Conformational Inversions and Rotational Isomerization and other aspects.Name: Benzyl(4-bromophenyl)sulfane
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