On February 5, 2021, Tlahuext-Aca, Adrian; Lee, Sarah Yunmi; Sakamoto, Shu; Hartwig, John F. published an article.Recommanded Product: 321-28-8 The title of the article was Direct Arylation of Simple Arenes with Aryl Bromides by Synergistic Silver and Palladium Catalysis. And the article contained the following:
The direct, catalytic arylation of simple arenes in small excess with aryl bromides was disclosed. The developed method did not require the assistance of directing groups and relies on a synergistic catalytic cycle in which phosphine-ligated silver complexes cleave the aryl C-H bond, while palladium catalysts enable the formation of the biaryl products. Mechanistic experiments, including kinetic isotope effects, competition experiments, and hydrogen-deuterium exchange, support a catalytic cycle in which cleavage of the C-H bond by silver is the rate-determining step. The experimental process involved the reaction of 1-Fluoro-2-methoxybenzene(cas: 321-28-8).Recommanded Product: 321-28-8
The Article related to arene aryl bromide synergistic palladium silver catalyst regioselective arylation, biaryl preparation, c鈥揾 activation, aryl bromides, direct arylation, palladium and silver catalysts, synergistic catalysis and other aspects.Recommanded Product: 321-28-8
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Ether – Wikipedia,
Ether | (C2H5)2O – PubChem