Kawasaki, Tairin et al. published their research in Journal of the American Chemical Society in 2020 |CAS: 578-58-5

The Article related to alkylarene aldehyde iridium nickel catalyst dehydrogenative cross coupling, aryl ketone preparation, methylamide aldehyde iridium nickel catalyst dehydrogenative cross coupling, amino ketone preparation and other aspects.Reference of 2-Methylanisole

On February 19, 2020, Kawasaki, Tairin; Ishida, Naoki; Murakami, Masahiro published an article.Reference of 2-Methylanisole The title of the article was Dehydrogenative Coupling of Benzylic and Aldehydic C-H Bonds. And the article contained the following:

A photoinduced dehydrogenative coupling reaction between benzylic and aldehydic C-H bonds was reported. When a solution of an alkylbenzene and an aldehyde in Et acetate was irradiated with visible light in the presence of iridium and nickel catalysts, a coupled 伪-aryl ketone was formed with evolution of dihydrogen. An analogous C-C bond forming reaction occurs between a C-H bond next to the nitrogen of an N-methylamide and an aldehydic C-H bond to produce an 伪-amino ketone. These reactions provide a straightforward pathway from readily available materials leading to valued structural motifs of pharmacol. relevance. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Reference of 2-Methylanisole

The Article related to alkylarene aldehyde iridium nickel catalyst dehydrogenative cross coupling, aryl ketone preparation, methylamide aldehyde iridium nickel catalyst dehydrogenative cross coupling, amino ketone preparation and other aspects.Reference of 2-Methylanisole

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem