On February 19, 2021, Falk, Eric; Gasser, Valentina C. M.; Morandi, Bill published an article.SDS of cas: 321-28-8 The title of the article was Synthesis of N-Alkyl Anilines from Arenes via Iron-Promoted Aromatic C-H Amination. And the article contained the following:
We report both an intermol. C-H amination of arenes to access N-methylanilines and an intramol. variant for the synthesis of tetrahydroquinolines. A newly developed, highly electrophilic aminating reagent was key for the direct synthesis of unprotected N-methylanilines from simple arenes. The reactions display a broad functional group tolerance and employ catalytic amounts of a benign iron salt under mild reaction conditions. The experimental process involved the reaction of 1-Fluoro-2-methoxybenzene(cas: 321-28-8).SDS of cas: 321-28-8
The Article related to arene oxymethylammonium triflate iron catalyst regioselective amination, methyl arylamine preparation, tosyloxy phenylpropyl carbamate iron catalyst regioselective amination, tetrahydroquinoline preparation and other aspects.SDS of cas: 321-28-8
Referemce:
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