Durka, Krzysztof; Klis, Tomasz; Serwatowski, Janusz; Wozniak, Krzysztof published an article in 2011, the title of the article was Functionalization of some benzylthioarylboronic acids by benzylic lithiation of their N-butyldiethanolamine esters or lithium (triisopropoxy)borates.Quality Control of Benzyl(4-bromophenyl)sulfane And the article contains the following content:
The reaction of benzylthioarylboronic acids protected as N-butyldiethanolamine esters or as triisopropoxyborates with organolithium bases or lithium diisopropylamide (LDA) has been investigated. The benzylic lithiation occurs selectively using LDA at -68掳. The stability of the resultant borio-lithio intermediates is strongly influenced by the position of the boron atom in the Ph ring. The reaction with various electrophiles affords new arylboronic acids substituted in the benzylic position. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Quality Control of Benzyl(4-bromophenyl)sulfane
The Article related to functionalization benzylthioarylboronic acid butyldiethanolamine ester triisopropoxyborate benzylic lithiation, silyl ethylthiomethyl phenylboronic acid preparation crystal mol structure and other aspects.Quality Control of Benzyl(4-bromophenyl)sulfane
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