Sun, Kai et al. published their research in Science China: Chemistry in 2015 |CAS: 321-28-8

The Article related to arylsaccharin regioselective preparation mechanism, saccharin arene copper catalyst amination regioselective, arylisothiazolone regioselective preparation mechanism, isothiazolone arene copper catalyst amination regioselective and other aspects.Name: 1-Fluoro-2-methoxybenzene

On August 31, 2015, Sun, Kai; Li, Yan; Zhang, Qian published an article.Name: 1-Fluoro-2-methoxybenzene The title of the article was Copper-catalyzed arenes amination with saccharins. And the article contained the following:

Synthesis of N-arylsaccharins I [R = 4-C6H5C6H4, C6H5, 1-naphthyl, etc.] and N-arylisothioazolones e.g. II [R1 = CH3, R2 = 4-ClC6H4] via copper-catalyzed direct C-N bond formation of simple arenes with saccharins/isothiazolones under relatively mild conditions was developed. This work provided a new method for oxidative coupling of aromatic C(sp2)-H bonds and N-H bonds by using arenes as limiting reagents. The experimental process involved the reaction of 1-Fluoro-2-methoxybenzene(cas: 321-28-8).Name: 1-Fluoro-2-methoxybenzene

The Article related to arylsaccharin regioselective preparation mechanism, saccharin arene copper catalyst amination regioselective, arylisothiazolone regioselective preparation mechanism, isothiazolone arene copper catalyst amination regioselective and other aspects.Name: 1-Fluoro-2-methoxybenzene

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem