《Phthalimide-Carried Disulfur Transfer To Synthesize Unsymmetrical Disulfanes via Copper Catalysis》 was written by Zou, Jiaoxia; Chen, Jinhong; Shi, Tao; Hou, Yongsheng; Cao, Fei; Wang, Yongqiang; Wang, Xiaodong; Jia, Zhong; Zhao, Quanyi; Wang, Zhen. Formula: C12H10S2This research focused onunsym disulfane preparation; phthalimide disulfur boronic acid cross coupling copper catalyst. The article conveys some information:
A versatile Cu-catalyzed cross-coupling reaction to various unsym. disulfanes R1SSR2 (R1 = Bn, Ph, 4-ClC6H4, etc.; R2 = 4-BrC6H4, 4-NCC6H4, 2-naphthyl, etc.) has been presented, from phthalimide-carried disulfur transfer reagents and com. available boronic acids under mild and practical conditions. The method features the unprecedented use of phthalimide-carried disulfurating reagents (Harpp reagent) in cross-coupling chem. and is highlighted by the broad substrate scopes, even applicable for the transfer of aryl-disulfur moieties (ArSS-). Notably, the robustness of this methodol. is shown by the late-stage modification of bioactive scaffolds of coumarin, estrone, and captopril. The results came from multiple reactions, including the reaction of 1,2-Diphenyldisulfane(cas: 882-33-7Formula: C12H10S2)
1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.Ethers do have nonbonding electron pairs on their oxygen atoms, and they can form hydrogen bonds with other molecules (alcohols, amines, etc.) that have O―H or N―H bonds. The ability to form hydrogen bonds with other compounds makes ethers particularly good solvents for a wide variety of organic compounds and a surprisingly large number of inorganic compounds.Formula: C12H10S2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem