Recommanded Product: 2-(Benzyloxy)acetaldehydeIn 2021 ,《Photoredox-catalyzed aminofluorosulfonylation of unactivated olefins》 was published in Chemical Science. The article was written by Zhong, Tao; Yi, Ji-Tao; Chen, Zhi-Da; Zhuang, Quan-Can; Li, Yong-Zhao; Lu, Gui; Weng, Jiang. The article contains the following contents:
The first three-component aminofluorosulfonylation of unactivated olefins, e.g., cyclohex-2-en-1-yl N-(4-chlorophenyl)carbamate by merging photoredox-catalyzed proton-coupled electron transfer (PCET) activation with radical relay processes has been described. Various aliphatic sulfonyl fluorides featuring a privileged 5-membered heterocyclic core compounds, e.g., I have been efficiently afforded under mild conditions with good functional group tolerance. The synthetic potential of the sulfonyl fluoride products has been examined by diverse transformations including SuFEx reactions and transition metal-catalyzed cross-coupling reactions. Mechanistic studies demonstrate that amidyl radicals, alkyl radicals and sulfonyl radicals are involved in this difunctionalization transformation. In the experiment, the researchers used 2-(Benzyloxy)acetaldehyde(cas: 60656-87-3Recommanded Product: 2-(Benzyloxy)acetaldehyde)
2-(Benzyloxy)acetaldehyde(cas: 60656-87-3) is a non-natural aldehyde. It undergoes enantioselective Mukaiyama aldol reaction with silylketene acetal nucleophiles in the presence of C2-symmetric bis(oxazolinyl)pyridine Cu(II) complex (catalyst).Recommanded Product: 2-(Benzyloxy)acetaldehyde
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