Formula: C8H8O3In 2019 ,《Syntheses, structures and Hirschfeld analyses of trinuclear Ni(Π) salamo-type complexes》 was published in Wuji Huaxue Xuebao. The article was written by Yu, Meng; Mu, Hao-ran; Liu, Ling-zhi; Li, Na; Bai, Yang; Dong, Xiu-yan. The article contains the following contents:
Two newly designed complexes, {[Ni(L1)(n-propanol)]2(OAc)2Ni}·2(n-propanol) (1) and {[Ni(L2)(n-butanol)]2(OAc)2Ni}·2(n-butanol) (2) derived from tetradentate Salamo-type chelating ligands (H2L1=5-methoxy-2,2′-(ethylenedioxybis(azomethine))diphenol and H2L2=4,4′-dinitro-2,2′-(ethylenediyldioxybis(nitrilomethylidyne))diphenol) have been synthesized and characterized by elemental analyses, IR and UV-Vis spectra, Hirschfeld surfaces analyses and single crystal X-ray crystallog. X-ray crystallog. analyses showed that complexes 1 and 2 are all sym. trinuclear Ni(Π) complexes. Nickel(Π) in both 1 and 2 is hexa-coordinated, forming a twisted octahedral geometry. Both crystal structure and Hirschfeld surface anal. indicate that 1 and 2 form stable one-dimensional chain and two-dimensional supramol. structures, resp., by intermol. hydrogen bonding. The results came from multiple reactions, including the reaction of 2-Hydroxy-4-methoxybenzaldehyde(cas: 673-22-3Formula: C8H8O3)
2-Hydroxy-4-methoxybenzaldehyde(cas: 673-22-3) is the main component of root bark essential oil of Periploca sepium Bunge. It is a potential tyrosinase inhibitor present in African medicinal plants. 2-Hydroxy-4-methoxybenzaldehyde was used in the synthesis of Schiff base ligand.Formula: C8H8O3
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem