Trofimova, Alina; Holownia, Aleksandra; Tien, Chieh-Hung; Sirvinskas, Martynas J.; Yudin, Andrei K. published an article in 2021. The article was titled 《Acylboronates in Polarity-Reversed Generation of Acyl Palladium(II) Intermediates》, and you may find the article in Organic Letters.Name: 1-Bromo-3-methoxybenzene The information in the text is summarized as follows:
A catalytic cross-coupling process between aryl(pseudo)halides and boron-based acyl anion equivalent was reported for the synthesis of ketones RCOR1 [R = Me, cyclohexyl, Ph, etc.; R1 = Ph, 4-MeC6H4, 2-naphthyl, etc.]. This mode of acylboronate reactivity represents polarity reversal, which was supported by the observation of tetracoordinated boronate and acyl palladium(II) species by 11B, 31P NMR, and mass spectrometry. A broad scope of aliphatic and aromatic acylboronates was examined, as well as a variety of aryl(pseudo)halides. In the part of experimental materials, we found many familiar compounds, such as 1-Bromo-3-methoxybenzene(cas: 2398-37-0Name: 1-Bromo-3-methoxybenzene)
1-Bromo-3-methoxybenzene(cas: 2398-37-0) can be used in chemical reaction as intermediates to obtain target materials such as dyes, pharmaceuticals, perfumes, photoinitiators and agrochemicals.Name: 1-Bromo-3-methoxybenzene
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