The author of 《Ortho/Ipso Alkylborylation of Aryl Iodides》 were Sui, Xianwei; Grigolo, Thiago A.; O’Connor, Colin J.; Smith, Joel M.. And the article was published in Organic Letters in 2019. Application In Synthesis of 1-Iodo-2-methoxybenzene The author mentioned the following in the article:
This work describes a method for the difunctionalization of aryl iodides to generate polysubstituted arenes via Pd catalysis. The reaction hinges on the unique interplay between norbornene and the metal catalyst to impart a guided ortho C-H alkylation event followed by a programmatic ipso borylation to provide a diverse array of substituted arene products. The utility of this transformation is demonstrated through the functionalization of the boronic ester to a variety of valuable functionalities. In the experiment, the researchers used many compounds, for example, 1-Iodo-2-methoxybenzene(cas: 529-28-2Application In Synthesis of 1-Iodo-2-methoxybenzene)
1-Iodo-2-methoxybenzene(cas: 529-28-2) participates in palladium catalyzed enantioselective Heck arylation of 2,3-dihydrofuran in the presence of chiral ionic liquids containing L-prolinate and L-lactate anions and non-chiral quaternary ammonium cations.Application In Synthesis of 1-Iodo-2-methoxybenzene
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem